Recent advances in ring-opening metathesis polymerization, and application to synthesis of functional materials

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Recent advances in ring-opening metathesis polymerization, and application to synthesis of functional materials

This article reviews the development of catalysts for ring-opening metathesis polymerization (ROMP), synthesis of polymers bearing amino acids and peptides by ROMP of functionalized norbornenes, formation of aggregates and micelles, and applications of the polymers to medical materials. It also describes the control of monomer unit sequences, that is, living polymerization to synthesize block c...

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Alcohol is the answer! An inactive, air-stable, dimeric molybdenum alkylidyne complex is activated toward ring-opening alkyne metathesis polymerization (ROAMP) by the addition of methanol. The ROAMP is compatible with water and phenol-containing substrates and with the in situ photochemical generation of alkyne monomers from cyclopropenones.

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Catalytic living ring-opening metathesis polymerization.

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Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization

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ژورنال

عنوان ژورنال: Polymer Journal

سال: 2010

ISSN: 0032-3896,1349-0540

DOI: 10.1038/pj.2010.94